temporada |
jugador |
equipo |
goles |
| 1928/29 | PACO BIENZOBAS | REAL SOCIEDAD | 17 |
| 1929/30 | GUILLERMO GOROSTIZA | ATHLETIC DE BILBAO | 20 |
| 1930/31 | AGUSTÍN SAUTO "BATA" | ATHLETIC DE BILBAO | 27 |
| 1931/32 | GUILLERMO GOROSTIZA | ATHLETIC DE BILBAO | 12 |
| 1932/33 | MANUEL OLIVARES | REAL MADRID | 16 |
| 1933/34 | ISIDRO LÁNGARA | REAL OVIEDO | 28 |
| 1934/35 | ISIDRO LÁNGARA | REAL OVIEDO | 27 |
| 1935/36 | ISIDRO LÁNGARA | REAL OVIEDO | 27 |
| 1939/40 | VÍCTOR UNAMUNO | ATHLETIC DE BILBAO | 20 |
| 1940/41 | PRUDEN SÁNCHEZ | ATLÉTICO DE MADRID | 30 |
| 1941/42 | EDMUNDO SUÁREZ "MUNDO" | VALENCIA C.F. | 27 |
| 1942/43 | MARIANO MARTÍN | F.C. BARCELONA | 32 |
| 1943/44 | EDMUNDO SUÁREZ "MUNDO" | VALENCIA C.F. | 27 |
| 1944/45 | TELMO ZARRAONAINDÍA | ATHLETIC DE BILBAO | 19 |
| 1945/46 | TELMO ZARRAONAINDÍA | ATHLETIC DE BILBAO | 24 |
| 1946/47 | TELMO ZARRAONAINDÍA | ATHLETIC DE BILBAO | 34 |
| 1947/48 | MANUEL FERNÁNDEZ "PAHIÑO" | CELTA DE VIGO | 23 |
| 1948/49 | CÉSAR RODRÍGUEZ | F.C. BARCELONA | 28 |
| 1949/50 | TELMO ZARRAONAINDÍA | ATHLETIC DE BILBAO | 25 |
| 1950/51 | TELMO ZARRAONAINDÍA | ATHLETIC DE BILBAO | 38 |
| 1951/52 | MANUEL FERNÁNDEZ "PAHIÑO" | REAL MADRID | 28 |
| 1952/53 | TELMO ZARRAONAINDÍA | ATHLETIC DE BILBAO | 24 |
| 1953/54 | ALFREDO DI STÉFANO | REAL MADRID | 27 |
| 1954/55 | JUAN ARZA IÑIGO | SEVILLA C.F. | 28 |
| 1955/56 | ALFREDO DI STÉFANO | REAL MADRID | 24 |
| 1956/57 | ALFREDO DI STÉFANO | REAL MADRID | 31 |
| 1957/58 | RICARDO ALÓS MANUEL BADENES ALFREDO DI STÉFANO |
VALENCIA C.F. REAL VALLADOLID REAL MADRID |
19 19 19 |
| 1958/59 | ALFREDO DI STÉFANO | REAL MADRID | 23 |
| 1959/60 | FERENC PUSKÁS | REAL MADRID | 26 |
| 1960/61 | FERENC PUSKÁS | REAL MADRID | 27 |
| 1961/62 | JUAN SEMINARIO | REAL ZARAGOZA | 25 |
| 1962/63 | FERENC PUSKÁS | REAL MADRID | 26 |
| 1963/64 | FERENC PUSKÁS | REAL MADRID | 20 |
| 1964/65 | CAYETANO RÉ | F.C. BARCELONA | 25 |
| 1965/66 | LUCIANO SÁNCHEZ "VAVÁ II" | ELCHE C.F. | 19 |
| 1966/67 | WALDO MACHADO | VALENCIA C.F. | 24 |
| 1967/68 | FIDEL URIARTE | ATHLETIC DE BILBAO | 22 |
| 1968/69 | AMANCIO AMARO JOSÉ EULOGIO GÁRATE |
REAL MADRID ATLÉTICO DE MADRID |
14 14 |
| 1969/70 | AMANCIO AMARO LUIS ARAGONÉS JOSÉ EULOGIO GÁRATE |
REAL MADRID ATLÉTICO DE MADRID ATLÉTICO DE MADRID |
16 16 16 |
| 1970/71 | JOSÉ EULOGIO GÁRATE CARLES REXACH |
ATLÉTICO DE MADRID F.C. BARCELONA |
17 17 |
| 1971/72 | ENRIQUE PORTA | GRANADA C.F. | 20 |
| 1972/73 | MARIANO ARIAS "MARIANÍN" | REAL OVIEDO | 19 |
| 1973/74 | ENRIQUE CASTRO "QUINI" | SPORTING DE GIJÓN | 20 |
| 1974/75 | CARLOS RUIZ | ATHLETIC DE BILBAO | 19 |
| 1975/76 | ENRIQUE CASTRO "QUINI" | SPORTING DE GIJÓN | 18 |
| 1976/77 | MARIO ALBERTO KEMPES | VALENCIA C.F. | 24 |
| 1977/78 | MARIO ALBERTO KEMPES | VALENCIA C.F. | 28 |
| 1978/79 | HANS KRANKL | F.C. BARCELONA | 29 |
| 1979/80 | ENRIQUE CASTRO "QUINI" | SPORTING DE GIJÓN | 24 |
| 1980/81 | ENRIQUE CASTRO "QUINI" | F.C. BARCELONA | 20 |
| 1981/82 | ENRIQUE CASTRO "QUINI" | F.C. BARCELONA | 26 |
| 1982/83 | POLI RINCÓN | REAL BETIS BALOMPIÉ | 20 |
| 1983/84 | JORGE DA SILVA JUAN GÓMEZ "JUANITO" |
REAL VALLADOLID REAL MADRID |
17 17 |
| 1984/85 | HUGO SÁNCHEZ | ATLÉTICO DE MADRID | 19 |
| 1985/86 | HUGO SÁNCHEZ | REAL MADRID | 22 |
| 1986/87 | HUGO SÁNCHEZ | REAL MADRID | 34 |
| 1987/88 | HUGO SÁNCHEZ | REAL MADRID | 29 |
| 1988/89 | BALTAZAR | ATLÉTICO DE MADRID | 35 |
| 1989/90 | HUGO SÁNCHEZ | REAL MADRID | 38 |
| 1990/91 | EMILIO BUTRAGUEÑO | REAL MADRID | 19 |
| 1991/92 | MANUEL SÁNCHEZ "MANOLO" | ATLÉTICO DE MADRID | 27 |
| 1992/93 | BEBETO | DEPORTIVO DE LA CORUÑA | 29 |
| 1993/94 | ROMARIO | F.C. BARCELONA | 30 |
| 1994/95 | IVÁN ZAMORANO | REAL MADRID | 28 |
| 1995/96 | JUAN ANTONIO PIZZI | C.D. TENERIFE | 31 |
| 1996/97 | LUIS NAZARIO DE LIMA "RONALDO" | F.C. BARCELONA | 34 |
| 1997/98 | CHRISTIAN VIERI | ATLÉTICO DE MADRID | 24 |
| 1998/99 | RAÚL GONZÁLEZ | REAL MADRID | 25 |
| 1999/00 | SALVA BALLESTA | RACING DE SANTANDER | 27 |
| 2000/01 | RAÚL GONZÁLEZ | REAL MADRID | 24 |
| 2001/02 | DIEGO TRISTÁN | DEPORTIVO DE LA CORUÑA | 21 |
| 2002/03 | ROY MAKAAY | DEPORTIVO DE LA CORUÑA | 29 |
| 2003/04 | LUIS NAZARIO DE LIMA "RONALDO" | REAL MADRID | 24 |
| 2004/05 | DIEGO FORLÁN | VILLARREAL C.F. | 25 |
| 2005/06 | SAMUEL ETO'O | F.C. BARCELONA | 26 |
| 2006/07 | RUUD VAN NISTELROOY | REAL MADRID | 25 |
| 2007/08 | DANI GÜIZA | R.C.D. MALLORCA | 27 |
| 2008/09 | DIEGO FORLÁN | ATLÉTICO DE MADRID | 32 |
| 2009/10 | LIONEL MESSI | F.C. BARCELONA | 34 |
| 2010/11 | CRISTIANO RONALDO | REAL MADRID | 41 |
| 2011/12 | LIONEL MESSI | F.C. BARCELONA | 50 |
| 2012/13 | LIONEL MESSI | F.C. BARCELONA | 45 |
| 2013/14 | CRISTIANO RONALDO | REAL MADRID | 31 |
| 2014/15 | CRISTIANO RONALDO | REAL MADRID | 48 |
| 2015/16 | LUIS SUÁREZ | F.C. BARCELONA | 40 |
| 2016/17 | LIONEL MESSI | F.C. BARCELONA | 37 |
| 2017/18 | LIONEL MESSI | F.C. BARCELONA | 34 |
| 2018/19 | LIONEL MESSI | F.C. BARCELONA | 36 |
| 2019/20 | LIONEL MESSI | F.C. BARCELONA | 25 |
| 2020/21 | LIONEL MESSI | F.C. BARCELONA | 30 |
| 2021/22 | KARIM BENZEMA | REAL MADRID | 27 |